Fabrication and Identification of Graphene Layers on Silicon Dioxide and Flexible PMMA Substrates
Graphene fabrication
Keywords:
Graphene, two-dimensional material, fabrication, micromechanical cleavageAbstract
: Graphene is a “wonder material” and rapidly rising star in all fields of physics. This strictly twodimensional material exhibits exceptionally high crystal quality and band structure. Graphene, building block of all graphitic materials, has emerged as an interesting material of the 21st century. This two-dimensional, single-layer sheet of sp2 hybridized carbon atoms has attracted tremendous attention and research interest, owing to its exceptional physical properties, such as high mobility, good thermal stability, excellent mechanical strength and high transparency. These properties make graphene a material of interest for many applications, for example in the fields of electronics, optoelectronics, photonics, composites as well as sensors. There are a number of methods for fabricating and characterizing graphene. Here in this work, graphene has been synthesized via micromechanical cleavage method and characterized via various techniques. Graphene is fabricated on oxidized silicon (Si/SiO2) and polymethyl methacrylate (PMMA) substrates. Si/SiO2 is a rigid substrate while PMMA is transparent, flexible and a versatile polymeric material having applications in flexible electronics. Micromechanical cleavage method is reproducible and large numbers of high quality graphene flakes were obtained by using this method on these two substrates. The graphene layers thus produced have been identified and characterized using optical microscopy, AFM and Raman spectroscopy showing single layer, bilayer, tri-layer and multi-layer graphene.
References
Blake, P. & E.W. Hill. Making graphene visible. Applied Physics Letters 91:1–4 (2007).
Bonaccorso, F. & Z. Sun. Graphene photonics and optoelectronics. Nature Photonics 4: 611-622 (2010).
Bae, S.& H. Kim. Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nature Nanotechnolgy 5: 574–578 (2010).
Novoselov, K.S. Electric field effect in atomically thin carbon films. Science 306: 666-669 (2004).
Avouris, P. Graphene: electronic and photonic properties and devices. Nano Letters 10: 4285– 4294(2010).
Wallace, P.R. The band theory of graphite. Physical Review Letters 71: 622-634 (1947).
McClure, J.W. Diamagnetism of graphite. Physical Review Letters 104: 666-671 (1956).
Slonczewski, J.C. & P.R. Weiss. Band structure of graphite. Physical Review Letters 109: 272-279 (1958).
Geim, A.K. &, K.S. Novoselov. The rise of graphene. Nature Materials 6: 183–191 (2007).
Castro Neto, A.H. The electronic properties of graphene. Reviews of Modern Physics 81: 109-162 (2009).
Nair, R.R. Fine structure constant defines transparency of graphene. Science 320: 1308–1308 (2008).
Lee, C.& X. Wei. Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321: 385-388 (2008).
Huang, X. & X. Qi. Graphene-based composites. Chemical Society Reviews 41: 666-686 (2011).
Lin, Y.M. 100-GHz transistors from wafer-scale epitaxial graphene. Science 327: 662 (2010).
Wu, Y. & Y. Lin. High frequency, scaled graphene transistor on diamond like carbon. Nature 472: 7478 (2011).
Liao, L. & Y.C. Lin. High speed graphene transistors with a self-aligned nanowire gate. Nature 467: 305308 (2010).
Novoselov, K.S. & V.I. Falko. A roadmap for graphene. Nature 490: 192–200 (2012).
Wang, Y. Understanding tapping-mode atomic force microscopy data on the surface of soft block copolymers. Surface Science 530: 136–148 (2003).
Ferrari, A.C. & J.C. Meyer. Raman spectrum of graphene and graphene layers. Physical Review Letters 97: 1–4 (2006).
Park, J.S. & A. Reina. G’ band raman spectra of single, double and triple layer graphene. Carbon
: 1303–1310 (2009).
Vidano, R.P. Observation of raman band shifting with exitation wavelength for carbons and graphites. Solid State Communications 39: 341-344 (1981).
Malard, L.M. & M.A. Pimenta. Raman spectroscopy in graphene. Physics Reports 473: 51–87 (2009).
Graf, D. & F. Molitor. Spatially resolved raman spectroscopy of single- and few-layer graphene. Nano Letters 7: 238–242 (2007).